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Humidity dependence of transport properties of composite materials used for thermochemical heat storage and thermal transformer appliances

dc.rights.licenseCC0en_US
dc.contributor.authorD'Ans, P.
dc.contributor.authorSkrylnyk, O.
dc.contributor.authorHohenauer, W.
dc.contributor.authorCourbon, E.
dc.contributor.authorMalet, L.
dc.contributor.authorDegrez, M.
dc.contributor.authorDescy, G.
dc.contributor.authorFrère, M.
dc.date.accessioned2024-11-07T23:53:26Z
dc.date.available2024-11-07T23:53:26Z
dc.date.issued2018
dc.identifier.issn2352152Xen_US
dc.identifier.urihttps://luck.synhera.be/handle/123456789/2833
dc.identifier.doi10.1016/j.est.2018.04.027en_US
dc.description.abstractJournal of Energy Storage 18 (2018) 160–170en_US
dc.description.abstractenWater sorption thermochemical heat storage is a promising way to provide dwellings with renewable central heating. It requires the use of several cubic meters of materials per dwelling. Depending on the design of the heating system, specific heat and mass transfer issues occur. For instance, the heat transfer rate in reactive medium and the kinetics of sorption process determine the system thermal power. In addition, the moisture propagation during inter-seasonal storage must be understood. In this paper, the influence of the water mass uptake on the apparent thermal conductivity and apparent mass diffusivity of solid material were studied. The studied material was a composite of calcium chloride (CaCl2) encapsulated in mesoporous silica with a salt content of 40–43 wt.%. The thermal conductivity was measured by the transient hot bridge method and varied from 0.13 to 0.16 W m−1 K−1, having a threshold at 0.14 g/g of water mass uptake. The apparent water mass diffusivity was studied using a diffusion column. The water diffusivity – concentration dependency was estab- lished by using the modified Hall method. The apparent diffusion coefficient ranged from 3×10−10 to 2 × 10−8 m2 s−1 in experimental conditions.en_US
dc.description.sponsorshipEURen_US
dc.language.isoENen_US
dc.publisherELSEVIERen_US
dc.relation.ispartofJournal of Energy Storageen_US
dc.rights.uriinconnuen_US
dc.subject.enComposite, Thermochemical heat storage, Calcium chloride, Mesoporous silica, Thermal conductivity, Water diffusivityen_US
dc.titleHumidity dependence of transport properties of composite materials used for thermochemical heat storage and thermal transformer appliancesen_US
dc.title.enHumidity dependence of transport properties of composite materials used for thermochemical heat storage and thermal transformer appliancesen_US
dc.typeArticle scientifiqueen_US
synhera.classificationPhysique, chimie, mathématiques & sciences de la terreen_US
synhera.institutionHE Libre de Bruxelles Ilya Prigogineen_US
synhera.cost.totalinconnuen_US
synhera.cost.apcinconnuen_US
synhera.cost.compinconnuen_US
synhera.cost.acccompinconnuen_US
dc.description.versionOuien_US
dc.rights.holderinconnuen_US
synhera.identifier.orcidwork104252023


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